That Chemist Archive Channel

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss five important papers in organic synthesis that were published in June 2022. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: first paper - https://www.doi.org/10.1021/acs.oprd.2c00104 second paper - https://www.doi.org/10.1002/anie.202206176 third paper - https://www.doi.org/10.1002/anie.202205673 fourth paper - https://www.doi.org/10.1002/anie.202204319 fifth paper - https://www.doi.org/10.1021/jacs.2c03978 hydrazone reference - https://www.doi.org/10.1071/CH9711437 Suárez Oxidation - https://www.doi.org/10.1016/S0040-4039(01)90085-1 Ruthenium-mediated oxidation - https://www.doi.org/10.1002/asia.202000134 *Bonus Papers* Sulfonimidamides from sulfinamides - https://www.doi.org/10.1021/acs.orglett.2c01099 Really cool difunctionalization of 3,6-anhydrosugars - https://www.doi.org/10.1021/acs.orglett.2c01243 EJ Corey shows some neat reactions of nitrosyl triflate & nitrous anhydride - https://www.doi.org/10.1021/acs.orglett.2c01466 Aldehydes to ketone-functionalized BCPs (from [1.1.1]propellane) - https://www.doi.org/10.1021/acs.orglett.2c01707 Baran makes enantioenriched dialkylcarbinol esters with Ni cross-coupling - https://www.doi.org/10.1021/jacs.2c04358 Synthesis of Pleuromutilin - https://www.doi.org/10.1021/jacs.2c04708 ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I expose a really bad article from a really bad journal. (This is a reupload from the old channel). https://www.patreon.com/thatchemist Community Discord: https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Sketchy Article - https://www.wjpr.net/abstract_file/1293 Bonus Sketchy Article - https://www.wjpr.net/abstract_file/4376 ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I show some of your greatest comments!!! This is the very first chempilation! Check out even more Chempilations! https://www.youtube.com/playlist?list=PL6OLqxmk7Rtx_0L7pPT5tzLD7rT-93riO https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss one of the worst experiences that I ever had in my research career. (This is a reupload from the old channel). https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Deoxofluor paper - https://doi.org/10.1055/s-2002-35626 ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I JUDGE functional groups, and decide which ones smell best and worst! https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: difluorobenzodioxole paper - https://www.doi.org/10.1021/acs.joc.0c01729 ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I reminisce about the time that I tried to make sodium tetrathiooxalate :( https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Amalgam article - https://www.doi.org/10.1002/cber.19270601120 DallE - https://huggingface.co/spaces/dalle-mini/dalle-mini ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss how research conferences work! https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss a retracted paper from Green Chemistry, where the authors use "magnetized water" for aromatic C-N bond formation. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Retracted article - https://www.doi.org/10.1039/D0GC01329C ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I show 5 absolutely astonishing blue chemicals! https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: https://en.wikipedia.org/wiki/Trifluoronitrosomethane https://upload.wikimedia.org/wikipedia/commons/8/86/Lactarius_indigo_48568_edit.jpg ChemicalForce Ozone - https://www.youtube.com/watch?v=ao4b_pEiYno NileRed Indigo - https://www.youtube.com/watch?v=6yhR242MnwA ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss five really useful lab tricks, which makes your lab life a little bit easier :) https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ----------------------------------------------------------------------------- Amazon Affiliate Link: Digital Thermocouple - https://amzn.to/3mNlcKo ----------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss many of the possible things that bad bosses do! Play along with a randomly generated Bingo card! Bingo: https://mfbc.us/m/zubh96s https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss YET ANOTHER Figueroa paper. This time he manages to make really strained rings using ninhydrin, substituting TWO nitro groups. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Sketchy Paper - https://www.doi.org/10.19261/cjm.2019.657 Ninhydrin review - https://www.doi.org/10.1002/047084289X.rn01848 Selenium paper - https://www.doi.org/10.1021/ol990791d ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I empirically decide which reducing agent is best! https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss the https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ My AgNO3 stain (0.2 g AgNO3, dissolved in 10 mL H2O, 10 mL MeOH). It isn't too light sensitive - it will form a slight black precipitate, but this doesn't affect the quality of the stain). This stain is good for sulfur derivatives. ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Great solvent group guide -https://www.yumpu.com/en/document/view/2214408/laboratory-chromatography-guide-buchi-labortechnik-gmbh NotVoodooX- http://www.chem.rochester.edu/notvoodoo/pages/chromatography.php?page=stains_dips A list of good stains - https://www.chemistry.mcmaster.ca/adronov/resources/Stains_for_Developing_TLC_Plates.pdf Seebach's magic stain: 25 g polymolybdic acid 10 g cerium (IV) sulfate 60 ml conc. H2SO4 940 ml H2O (from) https://www.scripps.edu/baran/images/grpmtgpdf/Holte_Feb_11.pdf ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss some of the common mistakes that people make when they are doing labwork. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ NotVoodooX - http://www.chem.rochester.edu/notvoodoo/pages/rookie_mistakes.php https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss the main considerations when preparing a supplemental information (for organic chemistry papers). https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Example 1 - https://www.doi.org/10.1039/C3CC43725F Example 2 - https://www.doi.org/10.1021/acs.orglett.9b02513 Example 3 - https://www.doi.org/10.1021/jacs.7b06044 Example 4 - https://www.doi.org/10.1021/ol500612n Example 5 - https://www.doi.org/10.1021/acs.orglett.7b03841 Example 6 - https://www.doi.org/10.1002/chem.201303699 Example 7 - https://www.doi.org/10.1002/anie.201002310 Example 8 - https://www.doi.org/10.1002/anie.201703841 ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss another really bad paper from Super Figueroa! He once-again wows us with the magic he is able to do using acetonitrile - what an absolute legend. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Super Figueroa - https://www.doi.org/10.1002/jhet.4189 ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I answer your questions! Make sure you leave a comment if you want me to do more Q&A's in the future! I had the wrong link for edX - it is edX.org https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links: Org Syn - http://www.orgsyn.org/demo.aspx?prep=cv6p1019 consulting email - contactthatchemist@gmail.com organic chemistry portal - https://www.organic-chemistry.org/ Baran Lab - https://www.youtube.com/channel/UCqfuQDFKYu63EmnCsNNOHSQ edX - https://www.edx.org/ ReactionFlash - https://apps.apple.com/us/app/reactionflash/id432080813 ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss the use of... carrots as reducing agents for ketones. Yes this is real, no it isn't a joke, yes it is hilarious. I want to give a huge thank you to the members of the Discord that made this video possible! Conditions for the first reduction - 100 mg acetophenone, 70 ml water, 10 g carrot. Upon reprocessing the spectra, the ratio of product to SM was 62% prod/38% SM. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Organic Chemistry Portal - https://www.organic-chemistry.org/chemicals/reductions/carrots.shtm JOC - https://www.doi.org/10.1021/jo010399p Org Lett - https://www.doi.org/10.1021/ol8029214 Ben List - https://www.doi.org/10.1055/s-0029-1216574 ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, Tom and I rank several notable energetic compounds! Links to Tom's Channels: Explosions&Fire - https://www.youtube.com/c/ExplosionsFire2 Extractions&Ire - https://www.youtube.com/c/ExtractionsIre https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss the prevalence of allylbenzene https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Cloves - https://www.doi.org/10.1021/jf060608c Sassafras - https://www.doi.org/10.1055/s-2006-959379 Anise - https://www.doi.org/10.1021/jf0257493 Fennel - https://www.doi.org/10.1080/0972060X.2011.10643978 Tarragon - https://www.doi.org/10.1177/1934578X1501000839 Parsley - https://www.doi.org/10.3390/foods5010018 Black Caraway - https://www.doi.org/10.1002/jsfa.3824 Octotea opifera Mart - https://www.doi.org/10.1080/10575630108041276 Croton hieronymi Root - https://www.doi.org/10.1080/10412905.2005.9698927 Chemistry of Spices Parthasarathy VA, Chempakam B, Zachariah TJ, editors. Cabi; 2008. ---------------------------------------------------------------------------------------------------------------------------------- ------- Amazon Affiliate Link: Napoleon's Buttons: 17 Molecules that Changed History https://amzn.to/3tgnK7t ------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss a paper from SN Applied Sciences, where the authors demonstrate some unprecedented chemistry using acetonitrile. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Sketchy Article - https://www.doi.org/10.1007/s42452-019-0378-7 ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss the types of conflict that you may experience in the research lab, as well as methods of resolving them. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss how to record a presentation without having it look and sound like complete trash. This video was recorded without doing any editing whatsoever. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ ------------------------------------------------------------------------------ Amazon Affiliate Links CAD Audio U37 USB Studio Condenser Recording Microphone - https://amzn.to/3x9pe65 Neewer Professional Microphone Pop Filter - https://amzn.to/3M0zGkp ------------------------------------------------------------------------------ https://rumblevideoarchive.wordpress.com/

Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss the radical, nucleophilic, and electrophilic trifluoromethylation in C-CF3 bond forming reactions. https://www.patreon.com/thatchemist Community Discord - https://discord.gg/QWNPETtPcZ I forgot to mention in the video that the Ritter lab developed a TTF-CF3 reagent, which is promising as a versatile trifluoromethylating agent: https://doi.org/10.1021/jacs.1c02606 ---------------------------------------------------------------------------------------------------------------------------------- Links to articles discussed in this episode: Xe - https://www.doi.org/10.2174/978160805198410602010061 radical CF3 review - https://www.doi.org/10.1039/D1CS00200G OG Langlois - https://www.doi.org/10.1016/0040-4039(91)80524-A Langlois review - https://www.doi.org/10.1002/slct.202103867 Caffeine - https://www.doi.org/10.1073/pnas.1109059108 CF3SO2Cl - https://www.doi.org/10.1038/nature10647 CF3I - https://www.doi.org/10.1002/anie.201101861 TMS-CF3 review - https://www.doi.org/10.1021/cr400473a CuCF3 review - https://www.doi.org/10.1055/s-0037-1611776 Best CuCF3 - https://www.doi.org/10.1039/C6RA10302B cat. copper - https://www.doi.org/10.1002/chem.201405677 CF3H - https://www.doi.org/10.1126/science.1227859 Weibreb amide - https://www.doi.org/10.1039/C2CC35037H ketone - https://www.doi.org/10.1002/ejoc.201101038 acyl phosphonium - https://www.doi.org/10.1002/chem.202102854 Trifluoromethylator - https://www.doi.org/10.1002/anie.201100633 silane - https://www.doi.org/10.1002/anie.201601163 Umemoto review - https://www.doi.org/10.1039/C4OB00671B Togni review - https://www.doi.org/10.1021/cr500223h Sulfoximinine - https://www.doi.org/10.1002/chem.202005104 alkenes - https://www.doi.org/10.1021/ja401022x imidazolidinone - https://www.doi.org/10.1021/ja100748y ---------------------------------------------------------------------------------------------------------------------------------- https://rumblevideoarchive.wordpress.com/