Eruption of the Bromine Volcano
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Halogens are spooky, and they should always be treated with respect. In this video, we have lots of halogenated stories!
This is the 31st chempilation
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Production Assistant - ToAldous
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18
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Taming Organolithiums Using Organogels
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Important Papers covers various chemical reactions, mechanisms, and research papers in the field of organic chemistry, providing examples and explanations for each research paper.
In this video, I discuss five important papers in organic synthesis that were published in March 2023.
Make sure you share this series with other chemists in your network, especially ones who don't usually watch YouTube!
Support the Channel on Patreon - https://www.patreon.com/thatchemist
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Important Papers Playlist - https://youtube.com/playlist?list=PL6OLqxmk7RtyRkdJhXK8NWpT1krGNq1p4
-----------------------------------------
References:
First Paper – https://pubs.acs.org/doi/10.1021/jacs.3c01591
Second Paper – https://pubs.acs.org/doi/10.1021/jacs.2c12481
Third Paper – https://pubs.rsc.org/en/content/articlepdf/2023/sc/d3sc00001j
Fourth Paper – https://pubs.acs.org/doi/10.1021/acs.oprd.2c00351
Fifth Paper – https://www.nature.com/articles/s41557-023-01136-x
-----------------------------------------
Honorable mentions:
Rh Carbenes - https://doi.org/10.1021/jacs.3c00012
Electron Transfer - https://doi.org/10.1038/s41929-023-00925-4
Overcrowding Aromaticity - https://doi.org/10.1038/s41557-023-01149-6
Electrochemical C-H Activation - https://doi.org/10.1126/science.adg2866
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Which Neurotoxin is the Worst?
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In this video, we explore several nerve-racking chemicals and discuss the biomechanics of nerves. I used to be a mouthpipetter like you, until I took a poisoned arrow in the knee.
A huge thanks to @reformlabs1050 and @ToAldous – I also want to thank Ballerene from the Discord for early research.
Writer/Producer: That Chemist
Editor/Animator: Reform Labs
Researcher/Production Assistant: Aldous
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------------------------------------------------------------
References:
Nerve Agent Tierlist - https://www.youtube.com/watch?v=5IFsaBBav78
neuron count in different species - https://doi.org/10.1073/PNAS.1201895109/
Nerves send signals - https://doi.org/10.1038/nn.4157.
Neurotransmitters - https://mind.ilstu.edu/curriculum/neurons_intro/neurons_intro.html
Synaptic Transmission - https://psych.athabascau.ca/html/Psych402/Biotutorials/animations/synapse.shtml
Neurotransmitter reuptake - https://doi.org/10.1101/CSHPERSPECT.A005595.
Hormones, Peptides, and Neurotransmitters and Their Role in Obesity - https://doi.org/10.1177/1559827617716376.
Melatonin - https://doi.org/10.3390/BRAINSCI9100285.
The Role of Brain Gaseous Neurotransmitters in Anxiety - https://doi.org/10.1007/S43440-021-00242-2.
Reactive Oxygen Species - https://doi.org/10.3389/FCELL.2021.628157/BIBTEX.
Alcohol, Oxidative Stress, and Free Radical Damage - https://doi.org/10.1079/pns2006496.
Toxicity of organomercury compounds - https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3183295/
Tetrodotoxin - https://www.cdc.gov/niosh/ershdb/emergencyresponsecard_29750019.html
BOTULINUM TOXIN - https://doi.org/10.4103/0019-5154.60343.
Tetraethylammonium - https://doi.org/10.1016/B978-0-12-801238-3.97466-X.
Toxiferine - https://www.sciencedirect.com/topics/pharmacology-toxicology-and-pharmaceutical-science/toxiferine
N-Hexane - https://doi.org/10.1136/jnnp.50.3.269.
MPP+ - https://www.sciencedirect.com/topics/medicine-and-dentistry/mpp
Epa, U.; of Water, O. Health Effects Support Document for the Cyanobacterial Toxin Anatoxin-A Office of Water Mail Code 4304T United States Environmental Protection Agency. 2015.
Elucidating the Neurotoxicity of the Star Fruit - https://doi.org/10.1002/ANIE.201305382.
Tubocurarine Chloride - https://www.sciencedirect.com/topics/pharmacology-toxicology-and-pharmaceutical-science/tubocurarine-chloride
The Phycotoxin Domoic Acid as a Potential Factor for Oxidative Alterations Enhanced by Climate - https://doi.org/10.3389/FPLS.2020.576971/BIBTEX.
Strychnine - https://www.sciencedirect.com/topics/medicine-and-dentistry/strychnine
Tetraethyllead - http://dx.doi.org/10.1136/oem.16.3.191
https://link.springer.com/article/10.1007/s13181-010-0034-5
https://doi.org/10.2131/jts.15.SupplementIV_125
Chlorpyrifos - https://www.epa.gov/ingredients-used-pesticide-products/chlorpyrifos
Tetramethylenedisulfotetramine -https://doi.org/10.1073/PNAS.1407379111/SUPPL_FILE/PNAS.1407379111.SAPP.PDF.
Structure-Toxicity Relationships of 1-Substituted-4-Alkyl-2,6,7-Trioxabicyclo[2.2.2.]Octanes - https://doi.org/10.1016/0041-008X(79)90323-5.
Neosaxitoxin - https://www.sciencedirect.com/topics/pharmacology-toxicology-and-pharmaceutical-science/neosaxitoxin
Carbon Disulfide - https://pubmed.ncbi.nlm.nih.gov/23331301/
https://pubmed.ncbi.nlm.nih.gov/27900598/
https://doi.org/10.1515/dmdi.1988.6.3-4.275
Tetramethylenedisulfotetramine - https://doi.org/10.3390/TOXICS6030051.
Aldicarb - https://www.sciencedirect.com/topics/neuroscience/aldicarb
Batrachotoxin - https://www.sciencedirect.com/topics/neuroscience/batrachotoxin
Resiniferatoxin - an overview | ScienceDirect Topics https://www.sciencedirect.com/topics/neuroscience/resiniferatoxin
5,7-Dihydroxytryptamine - https://doi.org/10.1016/j.brainres.2007.02.052
Chloramphetamine - https://doi.org/10.1016/0006-2952(86)90332-1
Oxidopamine - https://www.sciencedirect.com/topics/neuroscience/oxidopamine
Penitrem A - https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/penitrem-a
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List of molecules for this video: Ethanol, Tetrodotoxin, Botulinum toxin, Tetraethylammonium, Methylmercury, Toxiferine, n-Hexane, MPP+, Anatoxin-A, Caramboxin, Turbocurarine chloride, Domoic acid, Strychnine, Tetraethyllead, Chlorpyrifos, TBPO, Neosaxitoxin, Carbon disulfide, TETS, Aldicarb, Resiniferatoxin, Batrachotoxin, 5,7-dihydroxytryptamine, Para-chloroamphetamine, Oxidopamine, Penitrem A.
https://rumblevideoarchive.wordpress.com/
39
views
Late-Stage Methylation of Drug Molecules
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Important Papers covers various chemical reactions, mechanisms, and research papers in the field of organic chemistry, providing examples and explanations for each research paper.
In this video, I discuss five important papers in organic synthesis that were published in February 2023.
Make sure you share this series with other chemists in your network, especially ones who don't usually watch YouTube!
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Important Papers Playlist - https://youtube.com/playlist?list=PL6OLqxmk7RtyRkdJhXK8NWpT1krGNq1p4
-----------------------------------------
References:
First Paper – https://doi.org/10.1021/acs.orglett.2c03840
Second Paper – https://doi.org/10.1021/jacs.2c13396
Third Paper – https://doi.org/10.1021/jacs.2c13245
Fourth Paper – https://doi.org/10.1021/jacs.2c12699
Fifth Paper – https://doi.org/10.1021/jacs.2c13502
-----------------------------------------
Honorable mentions:
Hydroperoxides - https://doi.org/10.1021/acs.orglett.2c04233
Zizaene - https://doi.org/10.1021/jacs.2c10923
Tropylium - https://doi.org/10.1021/acscatal.2c06016
BCBs - https://doi.org/10.1021/jacs.2c13740
Alpha-fluorination - https://doi.org/10.1021/acs.orglett.3c00313
Germanes - https://doi.org/10.1021/jacs.2c12062
S(O)CF3 - https://doi.org/10.1021/acs.orglett.2c04243
Cyclobutanes - https://doi.org/10.1021/acs.joc.2c02564
Lysergic - https://doi.org/10.1021/jacs.2c13289
Vinyl bromide metathesis - https://doi.org/10.1021/jacs.2c13520
Thianthrene benzyne - https://doi.org/10.1021/jacs.2c13007
https://rumblevideoarchive.wordpress.com/
8
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Uncovering the Chemicals Involved in the East Palestine Train Derailment
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. How bad is it? Sorta bad, but it has impacted the lives of many local people greatly.
​@PracticalEngineeringChannel has a better up-to-date video on this: https://www.youtube.com/watch?v=uPno1IVTkFY
A lot of people asked me to make this video, I think I have had over 30 people request this video.
A huge thanks to Aldous, Mfernflower, Turtle, and Opossum Supremacist for their help :) I also want to thank Nathan.
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Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
----------------------------------------------------------------------------------------------------------------------------------
References:
Wikipedia has the most reliable information; it also has links to all the main sources (good luck searching literally anywhere else, unless you want to spend 2 days chasing leads, like I did) - https://en.wikipedia.org/wiki/2023_Ohio_train_derailment
train manifest - https://response.epa.gov/sites/15933/files/TRAIN%2032N%20-%20EAST%20PALESTINE%20-%20derail%20list%20Norfolk%20Southern%20document.pdf
https://response.epa.gov/site/site_profile.aspx?site_id=15933
propylene glycol MSDS - https://www.sigmaaldrich.com/CA/en/sds/sial/p4347
ethylhexyl acrylate MSDS - https://www.sigmaaldrich.com/CA/en/sds/aldrich/290815
butyl acrylate MSDS - https://www.sigmaaldrich.com/CA/en/sds/aldrich/234923
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11
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The Alarming Impact of AI on Society: Are You Ready for the Future?
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I used ChatGPT, DALL-E, and Descript for this video.
https://chat.openai.com/
https://labs.openai.com/
https://www.descript.com/
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References:
@TomScottGo - https://www.youtube.com/watch?v=jPhJbKBuNnA
@JonTronShow - https://www.youtube.com/watch?v=a-xGt-YvYys
@thespiffingbrit - https://www.youtube.com/watch?v=PVbOPhTcTxA
@Daxflame - https://www.youtube.com/watch?v=gqe_s_Q6xkU
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17
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Which Chemical is the Most Uncanny?
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In this video, I try harder than usual to pronounce plant names correctly. I also discuss several uncanny molecules, and rank them from most to least uncanny.
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------------------------------------------------------------
References:
Pyrimethamine nurd rage https://www.youtube.com/watch?v=5kZi3J2S52E
Triangulenes
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200461166
Amabiline
https://doi.org/10.1071%2FCH9672499
Folinic acid
https://www.drugs.com/monograph/leucovorin-calcium.html
Meralluride
https://doi.org/10.1016%2F0021-8707%2853%2990063-X
https://doi.org/10.1536%2Fihj.8.743
Peroxyacetyl nitrate
https://doi.org/10.1016%2FB978-0-12-382225-3.00433-3
Hyperforin
https://pubchem.ncbi.nlm.nih.gov/compound/441298
Graphullerene
https://www.nature.com/articles/s41586-022-05401-w
Calicheamicin
https://doi.org/10.7164%2Fantibiotics.42.558
https://doi.org/10.1073%2Fpnas.89.10.4608
https://pubs.acs.org/doi/10.1021/ja00051a063
https://doi.org/10.1126%2Fscience.1086695
Miroestrol
https://www.ftc.gov/os/2002/12/vdicmp.pdf
Nevirapine
https://www.drugs.com/monograph/nevirapine.html
Hypericin
http://pharmaxchange.info/press/2012/12/pharmacognosy-of-st-johns-wort/
JWH-176
https://doi.org/10.2174%2F0929867054020864
Xylindein
http://gallica.bnf.fr/ark:/12148/bpt6k30232/f110.image
Quinhydrone
https://doi.org/10.1016%2Fb978-0-12-555160-1.50017-4
Monocrotaline
https://doi.org/10.1152%2Fajplung.00212.2011
Longamide B
https://doi.org/10.1021/jo051555l
https://doi.org/10.1016/s0305-1978(00)00016-8
Lamotrigine
https://www.drugs.com/monograph/lamotrigine.html
Nitromemantine
https://doi.org/10.1016%2Fj.ceca.2009.12.009
https://doi.org/10.1038%2Fnrd1958
Atractyloside
https://doi.org/10.1016%2FS0278-6915%2898%2900002-7
https://doi.org/10.1016%2Fj.jep.2004.11.025
https://doi.org/10.1097%2F00007691-200012000-00001
Phytic acid
https://doi.org/10.1002%2Fmnfr.200900099
Triclofos
https://www.sciencedirect.com/science/article/pii/B9780080552323627977
Ichyothereol
https://doi.org/10.1021%2Fjo0104532
https://doi.org/10.1021%2Fja00950a044
Sivifene
http://adisinsight.springer.com/drugs/800002477
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All molecules for this Tierlist:
Triangulanes, Amabiline, Folinic acid, Meralluride, Peroxyacetyl nitrate, Hyperforin, Graphullerene, Calicheamicin, Miroestrol, Nevirapine, Hypericin, JWH-176, Xylindein, Quinhydrone, Agelongine, Monocrotaline, Longamide B, Lamotrigine, Nitromemantine, Atractyloside, Phytic acid, Triclofos, Ichyothereol, Sivifene
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32
views
Five Important Papers in Organic Synthesis (January 2023)
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This video is sponsored by Reaxys.
In this video, I discuss five important papers in organic synthesis that were published in January 2023.
Make sure you share this series with other chemists in your network, especially ones who don't usually watch YouTube!
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Backup Discord link - https://discord.gg/QWNPETtPcZ
Important Papers Playlist - https://youtube.com/playlist?list=PL6OLqxmk7RtyRkdJhXK8NWpT1krGNq1p4
-----------------------------------------
References:
First Paper – https://doi.org/10.1021/jacs.2c13207
Second Paper – https://doi.org/10.1021/jacs.2c11453
Third Paper – https://doi.org/10.1021/jacs.2c11295
Fourth Paper – https://doi.org/10.1021/acscatal.2c05293
Fifth Paper – https://doi.org/10.1021/acs.orglett.2c04144
--------------------------------------
Honorable Mentions:
Ca-H - https://doi.org/10.1021/acs.joc.2c02800
Formylation - https://doi.org/10.1021/acs.joc.2c02576
Addition to aldehydes - https://doi.org/10.1021/acs.joc.2c01843
I(III) diazo reagents - https://doi.org/10.1021/acs.orglett.2c04114
1,3,4-Oxadiazolines - https://doi.org/10.1021/acscatal.2c05319
Methylenation - https://doi.org/10.1021/acs.joc.2c02637
NHC boryl radical - https://doi.org/10.1021/jacs.2c10444
Nitroarenes - https://doi.org/10.1021/jacs.2c12450
https://rumblevideoarchive.wordpress.com/
8
views
The Stolen Cesium-137 Sample: A Cautionary Tale of Radiation Safety
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This video is packed with more wild lab stories - hopefully you never end up facing the same fate these people did!
This is the 30th chempilation
If you support the channel on Patreon, you get access to monthly Patreon-exclusive chempilations. I just posted a brand new one yesterday! https://www.patreon.com/thatchemist
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Thumbnail was made by DALL-E, title was suggested by ChatGPT.
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13
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Which Chemical is the Worst Carcinogen?
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss several carcinogens and discuss their designations according to the IARC (International Agency for Research on Cancer). Don't be a nugget, minimize your exposure to carcinogens!
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------------------------------------------------------------
References:
Medlife crisis video – https://www.youtube.com/watch?v=yNzQ_sLGIuA
Chloracne - https://upload.wikimedia.org/wikipedia/commons/5/5a/Chloracne-in-herbicide-worker.png
Hamiltons pharmacopeia - https://www.youtube.com/watch?v=zBYsY7g24r0
Risky chemicals Tierlist - https://www.youtube.com/watch?v=QfOYfBeP5KE
IARC Monographs
https://publications.iarc.fr/Book-And-Report-Series/Iarc-Monographs-On-The-Identification-Of-Carcinogenic-Hazards-To-Humans
Aristolochic acid I
https://doi.org/10.1016%2Fj.jep.2009.05.028
https://www.hongkongfp.com/2017/10/19/across-asia-liver-cancer-linked-herbal-remedies-study/
https://www.fda.gov/Food/DietarySupplements/Alerts/ucm096388.htm
IARC Vol 100A
Acetaldehyde
http://www.epa.gov/chemfact/s_acetal.txt
https://doi.org/10.1080%2F00365520902912563
https://doi.org/10.1371%2Fjournal.pone.0140013
IARC Vol 100E
Aflatoxins
https://doi.org/10.3109%2F10408444.2011.575766
IARC Vol 100F
4-Aminobiphenyl
https://www.ncbi.nlm.nih.gov/books/NBK304408/
https://doi.org/10.1016%2F0006-2952%2896%2900165-7
https://doi.org/10.1002%2Fijc.21173
IARC Vol 100F
Arecoline
https://doi.org/10.1016%2FS0014-827X%2801%2901091-6
https://pubmed.ncbi.nlm.nih.gov/3600615
IARC Vol 85
Agaritine
https://doi.org/10.1080%2F02652030802039903
IARC Vol 31
Benzene
https://doi.org/10.1289%2Fehp.93100293
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1568107/
IARC Vol 100F
Benzidine
http://www.cancer.org/docroot/PED/content/PED_1_3x_Known_and_Probable_Carcinogens.asp?sitearea=PED
https://web.archive.org/web/20100821232316/http://www.epa.gov/oppt/existingchemicals/pubs/actionplans/benzidine.html
IARC Vol 29
Benzo[a]pyrene
https://doi.org/10.1016%2FS0278-6915%2800%2900158-7
https://books.google.com/books?id=Fw_G7Sk382IC&q=Benzo%28a%29pyrene-7%2C8-dihydrodiol-9%2C10-epoxide+cas&pg=PA102
IARC Vol 92
Bis(chloromethyl)ether/chloromethyl methyl ether
https://doi.org/10.1002%2F14356007.a10_023
https://doi.org/10.1016%2Fs0013-9351%2889%2980059-3
https://ntp.niehs.nih.gov/ntp/roc/content/profiles/bis_chloromethyletherandtechnical-gradechloromethylmethylether.pdf
https://youtu.be/ErLv93PgiuM
http://www.epa.gov/iris/subst/0245.htm
IARC Vol 100F
Butadiene
https://doi.org/10.1002%2F14356007.a04_431.pub2
https://doi.org/10.1016%2FS1470-2045%2807%2970235-8
IARC Vol 100F
Cyclosporine
https://www.drugs.com/monograph/cyclosporine.html
https://www.ncbi.nlm.nih.gov/books/NBK304321/
IARC Vol 100A
Dichloropropane
http://www.mhlw.go.jp/stf/houdou/2r9852000002x6at.html
https://www.cdc.gov/niosh/npg/npgd0534.html
https://www.cdc.gov/niosh/idlh/78875.html
IARC Vol 110
Diethylstilbestrol
https://doi.org/10.1016%2FS0025-7125%2816%2932122-8
https://books.google.com/books?id=-tz4J4_hgdIC&pg=PA26
https://doi.org/10.1007%2Fs11096-005-3663-z
IARC Vol 100A
Ethylene oxide
https://doi.org/10.1023%2FA%3A1024891529592
IARC Vol 100F
Formaldehyde
https://doi.org/10.1002%2F14356007.a11_619
https://wwwn.cdc.gov/TSP/MMG/MMGDetails.aspx?mmgid=216&toxid=39
https://doi.org/10.1016%2Fj.mrrev.2008.07.002
IARC Vol 100F
Lindane
http://www3.cec.org/islandora/en/item/11389-north-american-regional-action-plan-lindane-and-other-hexachlorocyclohexane-isomers-final-en.pdf
https://www.atsdr.cdc.gov/toxprofiles/tp43.pdf
https://www.who.int/ipcs/publications/pesticides_hazard_rev_3.pdf
https://doi.org/10.1016%2FS1470-2045%2815%2900081-9
IARC Vol 113
Methoxsalen
http://www.cancer.org/cancer/cancercauses/othercarcinogens/generalinformationaboutcarcinogens/known-and-probable-human-carcinogens IARC Vol 100A
4,4'-Methylenebis(chloroaniline)
https://www.cdc.gov/niosh/npg/npgd0411.html
IARC Vol 100F
2-Naphthylamine
https://doi.org/10.1002%2F14356007.a17_009
https://www.cdc.gov/niosh/npg/npgd0442.html
IARC Vol 100F
NNN/NNK
https://doi.org/10.1093%2Fcarcin%2Fbgt162
https://doi.org/10.1073%2Fpnas.0506581102
http://nj.gov/health/eoh/rtkweb/documents/fs/2900.pdf
https://doi.org/10.3892%2Fijo.29.4.745
https://doi.org/10.3390%2Fijerph120809046
IARC Vol 100E
Polychlorinated ones
https://sciencedirect.com/science/article/abs/pii/0272059088901480
https://doi.org/10.1080%2F026520300283360
https://www.epa.gov/ingredients-used-pesticide-products/pentachlorophenol
IARC Vol 100F
Phenacetin
https://doi.org/10.1016%2FS0049-3848%2803%2900416-X
IARC Vol 100A
Sulfur mustard
IARC Vol 100F
Toluidine
https://doi.org/10.1006%2Fabbi.1999.1461
IARC Vol 100F
Trichloroethylene
IARC Vol 106
Vinyl chloride
IARC Vol 100F
I hit the character limit but there are a few more references :/
https://rumblevideoarchive.wordpress.com/
61
views
Safety Isn’t Optional – PPE Tierlist
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Use code POGCHEMISTJAN60 for 60% off your first box at
https://strms.net/ThatChemistFactorDecemberYT60
#ad
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In this video, I decide which PPE (Personal Protective Equipment) is the best, and which PPE is the worst.
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
https://rumblevideoarchive.wordpress.com/
7
views
The Diels Alder Reaction (IOC 50)
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. In this video, I discuss the Diels Alder reaction, including regular demand and inverse demand, the ortho/para rule, and endo/exo selectivity. I also briefly discuss molecular orbital theory.
This is the 50th video in the Introductory Organic Chemistry series.
playlist link - https://www.youtube.com/playlist?list=PL6OLqxmk7RtzLTsvdjQXsAO38aGuJj3e6
https://www.patreon.com/thatchemist
Community Discord - https://discord.gg/thatchemist
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Links to articles discussed in this episode:
phosphonate alkyne - https://www.doi.org/10.1016/j.tet.2011.03.076
isoindole maleimide - https://www.doi.org/10.1021/ja0658259
sulfone maleimide - https://www.doi.org/10.1021/ol201095b
tetracyanoethylene - https://www.doi.org/10.1002/chem.200700796
vinyl ether inverse DA - https://www.doi.org/10.1016/j.tet.2011.03.034
dihydrofuran inverse DA - https://www.doi.org/10.1016/S0040-4020(00)00937-6
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10
views
Five Important Papers in Organic Synthesis (December 2022)
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Download ReactionFlash for free using the following links:
Apple App Store:
https://apps.apple.com/app/apple-store/id432080813?pt=119296909&ct=ThatChemist-Ad3&mt=8
Google Play Store:
https://play.google.com/store/apps/details?id=ch.reaxys.reactionflash&hl=en_GB&gl=US&utm_campaign=reactionflash&utm_source=thatchemist-ad3&utm_medium=video&utm_content=descriptionlink&utm_term=ad3
This video is sponsored by Reaxys.
In this video, I discuss five important papers in organic synthesis that were published in December 2022.
Make sure you share this series with other chemists in your network, especially ones who don't usually watch YouTube!
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Backup Discord link - https://discord.gg/QWNPETtPcZ
Important Papers Playlist - https://youtube.com/playlist?list=PL6OLqxmk7RtyRkdJhXK8NWpT1krGNq1p4
-----------------------------------------
References:
First Paper – https://pubs.acs.org/doi/pdf/10.1021/jacs.2c11024
Second Paper – https://www.nature.com/articles/s41557-022-01087-9
Boron Chemistry Video – https://youtu.be/aFfSIQQnoq0
Background paper on metal carbenoids – https://pubs.acs.org/doi/pdf/10.1021/jacs.7b05457
Third Paper – https://pubs.acs.org/doi/pdf/10.1021/jacs.2c10570
Fourth Paper – https://pubs.acs.org/doi/pdf/10.1021/jacs.2c10856
Pinnick Oxidation Video – https://youtu.be/vCOx6XqrkQ4
Fifth Paper – https://www.science.org/doi/10.1126/science.abq1274
--------------------------------------
Honorable Mentions
Pyrimidines into pyrazoles - https://pubs.acs.org/doi/pdf/10.1021/jacs.2c10746
Aminoacylation - https://pubs.acs.org/doi/pdf/10.1021/jacs.2c11209
Multicomponent annulation - https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202210822
Difluorovinyl iodonium - https://doi.org/10.1038/s42004-022-00772-7
Thianthrenation - https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202214096
Asymmetric acyloin - https://pubs.acs.org/doi/pdf/10.1021/jacs.2c10072
Meta functionalization - https://www.nature.com/articles/s41557-022-01101-0
Remote oxidation - https://pubs.acs.org/doi/pdf/10.1021/jacs.2c11428
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16
views
A Chemtuber Christmas (The 12 Days of Labwork)
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Lyrics:
On the twelfth day of Labwork, my research gave to me
12 stopcocks leaking
11 pipettes breaking
10 beakers spilling
9 joints a-seizing
8 test tubes smoking
7 thiols reeking
6 fingers missing
5 Golden Tars
4 acid burns
3 close calls
2 dirty gloves, and
And a visit from the police
A huge thank you to all of the Chemtubers who contributed!
@ChemicalForce
@THYZOID
@Chemiolis
@NurdRage
@AdvancedTinkering
Tom and Nigel were encouraging, but they chose to abstain from having their beautiful voices contribute to this festive season in a musical medium.
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
The way I made this song was terrible - I used a synthesizer in LMMS, and MIDI-mapped the song, then I recorded my audio in OBS, and processed everyone's audio in Adobe Audition. Once Audition corrupted the entire project, and I redid it and exported it in one go, I used Premiere to piece the video together with the audio. (I know how to use Cubase, but I don't actively do anything music-related, so no license :/).
https://rumblevideoarchive.wordpress.com/
10
views
Best Moments from That Chemist 2022
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Here are the viewer-suggested highlights for the past year! Thank you for being amazing viewers, and mouthpipetting every single day. I also want to thank the people from Spicy who contributed FOOMPS for the end of the video!
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
0:00 – intro
0:10 – Toxic WJPR
0:32 – Rat chlorination
2:06 – cringe tierlist
2:20 – seriously stupid chlorine lasers
2:50 – deoxofluor
3:49 – Ex&F tierlist
4:00 – amino acid tierlist
7:30 – age restricted tierlist
8:07 – vaped smoke detector chempilation
10:13 – nuclear comments/chempit
10:58 – propofol incapacitating agent tierlist
12:59 – hair chemistry
13:53 – carrot chemistry
14:16 – cursed tierlist part 2 – fluoronium
15:08 – agrochemicals tierlist
15:33 – cursed molecules tierlist
15:40 - cursed tierlist part 2 – outro
15:44 – outro
15:57 - FOOMPS
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Videos referenced in order
Toxic WJPR - https://youtu.be/7YoCsLhbU0g
Rat chlorination - https://youtu.be/m2BI-FVl6fc
Cringe tierlist - https://youtu.be/OxZ1XShZt58
Seriously stupid chlorine lasers - https://youtu.be/x75A6vGrPuI
Deoxofluor - https://youtu.be/Psc6MgWMajk
Ex&F tierlist - https://youtu.be/Im5Y0ogGr0I
Amino acid tierlist - https://youtu.be/edSaOl08Cqs
Age restricted tierlist - https://youtu.be/u6wYwgGqGs8
Vaped smoke detector chempilation - https://youtu.be/14UggnpN39w
Nuclear comments/chempit - https://youtu.be/_iLOd9fPkXo
Propofol incapacitating agent tierlist - https://youtu.be/T9stdKOB22I
Hair chemistry - https://youtu.be/NCCl66O8BRw
Carrot chemistry - https://youtu.be/wkES6aHpWXk
Cursed tierlist part 2/fluoronium - https://youtu.be/7mCL-C13ZGw
Agrochemicals tierlist - https://youtu.be/6WfevwtLi44
Cursed molecules tierlist - https://youtu.be/ofLuq4Tyeus
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https://rumblevideoarchive.wordpress.com/
14
views
Five Important Papers in Organic Synthesis (November 2022)
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Download ReactionFlash for free using the following links:
Apple App Store:
https://apps.apple.com/app/apple-store/id432080813?pt=119296909&ct=ThatChemist-Ad2&mt=8
Google Play Store:
https://play.google.com/store/apps/details?id=ch.reaxys.reactionflash&hl=en_GB&gl=US&utm_campaign=reactionflash&utm_source=thatchemist-ad2&utm_medium=video&utm_content=descriptionlink&utm_term=ad2
This video is sponsored by Reaxys.
In this video, I discuss five important papers in organic synthesis that were published in November 2022.
Make sure you share this series with other chemists in your network, especially ones who don't usually watch YouTube!
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Backup Discord link - https://discord.gg/QWNPETtPcZ
Important Papers Playlist - https://youtube.com/playlist?list=PL6OLqxmk7RtyRkdJhXK8NWpT1krGNq1p4
-----------------------------------------
References:
First Paper – https://pubs.acs.org/doi/pdf/10.1021/acscatal.2c04010
Second Paper – https://pubs.acs.org/doi/pdf/10.1021/jacs.2c09244
Third Paper – https://pubs.acs.org/doi/pdf/10.1021/jacs.2c08989
Fourth Paper – https://www.science.org/doi/10.1126/science.ade6029
Fifth Paper – https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.2c03570
--------------------------------------
Papers I was an author on in the past month:
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202202862
https://pubs.acs.org/doi/10.1021/acs.orglett.2c03540
--------------------------------------
Honorable Mentions
3-Halogenation of pyridines - https://doi.org/10.1126/science.add8980
Cyclopropane pyridines - https://doi.org/10.1002/anie.202214507
R-F organocuprates - https://doi.org/10.1021/acs.orglett.2c03775
1,2,3-Triazenes - https://doi.org/10.1021/acs.joc.2c02082
Benzoylformates - https://doi.org/10.1021/jacs.2c09248
Decatungstate acetylation - https://doi.org/10.1021/acs.orglett.2c03142
Decatungstate epimerization - https://doi.org/10.1126/science.add6852
Sulfoxonium Ylides - https://doi.org/10.1038/s41467-022-34401-7
Bicyclo[3.1.1]heptanes - https://doi.org/10.1021/jacs.2c09733
https://rumblevideoarchive.wordpress.com/
16
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Which Chemicals are the Most Cursed?
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Back by popular demand, we have another cursed molecules tierlist!
First Cursed Tierlist - https://www.youtube.com/watch?v=ofLuq4Tyeus
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
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References:
Thiarubrine B - https://pubs.acs.org/doi/10.1021/ja00099a097
HIV - https://doi.org/10.1111/j.1751-1097.1993.tb02936.x
Cicutoxin - https://doi.org/10.1080/15563650902904332
https://doi.org/10.1002%2Fejoc.200801172
Hoye’s Witchcraft - https://doi.org/10.1021/acs.orglett.8b02473
Hypoglycin - https://doi.org/10.1016%2Fb978-0-12-801227-7.00004-4
Varacin - https://doi.org/10.1021/ja016495p
Dicyanoacetylene - https://doi.org/10.1021%2Fja01590a075
Titan - https://doi.org/10.1016%2FS0032-0633%2897%2900088-3
Syntin - https://web.archive.org/web/20090920132913/http://www.novosti-kosmonavtiki.ru/nk/forum-pic/Omar_NK2008-02.pdf
Diazodinitrophenol - http://babel.hathitrust.org/cgi/pt?id=njp.32101044011037;view=1up;seq=541
Cymoxanil - https://pubchem.ncbi.nlm.nih.gov/compound/Cymoxanil
Thiamethoxam - https://doi.org/10.1002%2Fps.365
Huperzine A - https://doi.org/10.1016%2FS0091-3057%2803%2900111-4
Pentaphenylpentaphospholane - https://youtu.be/uusXv4DhANw
Batrachotoxin - https://doi.org/10.1007%2FBF02152303
Orysastrobin - https://pubs.acs.org/doi/10.1021/jf202228p
Divinyl ether - https://csahq.org/docs/default-source/news-and-events-docs/csa-bulletin-docs/winter-2007/guedel_064.pdf?sfvrsn=60e3c646_2
Bixin - https://doi.org/10.1126%2Fscience.1085162
Toxoflavin - https://pubmed.ncbi.nlm.nih.gov/24542943/
C01-A042 - https://youtu.be/5IFsaBBav78
Guanitoxin - https://doi.org/10.1021%2Fja00202a057
Perfluorocubane - https://youtu.be/Tn9EANWD96s
Rocuronium bromide - https://doi.org/10.1002%2F14651858.CD002788.pub3
Melarsoprol - https://www.who.int/mediacentre/factsheets/fs259/en/
Ethchlorvynol - https://patents.google.com/patent/US2746900A/en
Lectka’s Illegal Fluoronium - https://www.nature.com/articles/s41467-021-25592-6
1,4,7-Trimethyloxatriquinane - https://pubs.acs.org/doi/10.1021/ja103880c
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Molecules for this tierlist - Thiarubrine B, Cicutoxin, Hoye’s Witchcraft, Hypoglycin, Varacin, Dicyanoacetylene, Syntin, Diazodinitrophenol, Cymoxanil, Thiamethoxam, Huperzine A, Pentaphenylpentaphospholane, Batrachotoxin, Orysastrobin, Divinyl ether, Bixin, Toxoflavin, C01-A042, Guanitoxin, Perfluorocubane, Rocuronium bromide, Melarsoprol, Ethchlorvynol, Lectka’s Illegal Fluoronium, 1,4,7-Trimethyloxatriquinane
Tierlist Playlist - https://www.youtube.com/playlist?list=PL6OLqxmk7Rtx7YVG6hOgVHAgisH-y8yIW
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Music (in order; Title - Artist):
Six Seasons - Unicorn Heads
Bonfire - An Jone
Friendly Dance - Nico Staf
Press Fuse - French Fuse
Target Fuse - French Fuse
Duh Fuse - French Fuse
Target Fuse - French Fuse
https://rumblevideoarchive.wordpress.com/
31
views
Failing Lab Inspection Day
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. If you practice chemistry - make sure you use protection (PPE).
This is the 29th chempilation
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
Incapacitating Agent Tierlist - https://youtu.be/T9stdKOB22I
Channel Update Video (on the 2nd Channel) - https://youtu.be/eoM-RCIMB3E
Chempilation Playlist - https://www.youtube.com/playlist?list=PL6OLqxmk7Rtx_0L7pPT5tzLD7rT-93riO
--------------------------------------
Music (title - artist):
Six Seasons - Unicorn Heads
Walking in the Sky - Nico Staf
Dulce Reggaeton - An Jone
https://rumblevideoarchive.wordpress.com/
4
views
Which Chemical has the Worst Abbreviation?
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. This time, we're ranking the abbreviations for chemicals! some chemicals have based abbreviations, while other chemicals have cursed ones.
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
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References:
NBA eEROS - https://doi.org/10.1002/047084289X.rb268.pub2
FAP paper - https://doi.org/10.1016/j.jfluchem.2005.04.017
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Molecules for this tierlist - BOC – tert-butoxycarbonyl, TIPS-Cl – Triisopropylsilyl chloride, MOM-Cl – Methoxymethyl chloride, CAMP – Cyclic adenosine monophosphate, TPAP – Tetrapropylammonium perruthenate, FOOF – Dioxygen difluoride, DABCO – 1,4-diazabicyclo[2.2.2]octane, DEADCAT – Diethyl azodicarboxylate, Cp* - Pentamethylcyclopentadienyl, BArF – Tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, DiPT – Diisopropyltryptamine, DOTA - 2,2′,2′′,2′′′-(1,4,7,10-Tetraazacyclododecane-1,4,7,10-tetrayl)tetraacetic acid, CAM – Ceric ammonium molybdate, PPi – inorganic pyrophosphate, TEA – Triethylamine, BCNU – 1,3-Bis(2-chloroethyl)-1-nitrosourea, BAIB / PIDA – Bis(acetoxy)iodobenzene / phenyliodine(III) diacetate, NBA – N-Bromoacetamide, CAN – ceric ammonium nitrate, dUMP – Deoxyuridine monophosphate, FAP – tris(perfluoroalkyl)trifluorophosphate, DAMN – Diaminomaleonitrile, SEX – Sodium ethyl xanthate.
Tierlist Playlist - https://www.youtube.com/playlist?list=PL6OLqxmk7Rtx7YVG6hOgVHAgisH-y8yIW
------------
Music (in order; Title - Artist):
Tropic Fuse - French Fuse
India Fuse - French Fuse
Positive Fuse - French Fuse
Duh Fuse - French Fuse
Press Fuse - French Fuse
Target Fuse - French Fuse
I Feel It All So Deeply - Bail Bonds
Rinse Repeat - DivKid
https://rumblevideoarchive.wordpress.com/
27
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Which Incapacitating Agent is the Most Effective?
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. This time, we're ranking incapacitating agents! The term incapacitating agent is defined by the United States Department of Defense as: "An agent that produces temporary physiological or mental effects, or both, which will render individuals incapable of concerted effort in the performance of their assigned duties." It describes an agent which renders a person unable to harm themselves or others, regardless of consciousness.
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
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References:
CS Gas Chempilation - https://youtu.be/9a7a11i9Ce4
WKUK PCP - https://www.youtube.com/watch?v=tFUvmZWf4hI
Hamilton's Pharmacopeia PCP - https://www.vicetv.com/en_us/video/a-positive-pcp-story/580fbc1befcfab397fd8c8b5
Scary book - Jared Ledgard, A Laboratory History of Chemical Warfare Agents - ISBN-13 number 978-0615136455
Nerve Agent Tierlist - https://www.youtube.com/watch?v=5IFsaBBav78
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Molecules for this tierlist - Agent 15 (BZ), DMHP (EA-2233), Nonivamide, GHB, Phenacyl chloride (CN/Mace), Chloroform, Xylyl bromide, Capsaicin (OC), CS gas (EA-1779), MPK (EA-1778), Ethanol, Sneeze Mace, CR gas (EA-3547), LSD (EA-1729), Halothane, Adamsite (DM), Chloral hydrate, Carfentanil, Rohypnol (roofies), Sodium thiopental, PCP (EA-2148), Ketamine, Fentanyl, Nitrous oxide, Propafol, Chloroacetone, Diimine (DIM), Bromobenzyl cyanide (BBC), Chloropicrin (PS)
Tierlist Playlist - https://www.youtube.com/playlist?list=PL6OLqxmk7Rtx7YVG6hOgVHAgisH-y8yIW
https://rumblevideoarchive.wordpress.com/
52
views
Five Important Papers in Organic Synthesis (October 2022)
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Download ReactionFlash for free using the following links:
Apple App Store:
https://apps.apple.com/app/apple-store/id432080813?pt=119296909&ct=ThatChemist-Ad1&mt=8
Google Play Store:
https://play.google.com/store/apps/details?id=ch.reaxys.reactionflash&hl=en_GB&gl=US&utm_campaign=reactionflash&utm_source=thatchemist-ad1&utm_medium=video&utm_content=descriptionlink&utm_term=ad1
This video is sponsored by Reaxys.
In this video, I discuss five important papers in organic synthesis that were published in October 2022.
Make sure you share this series with other chemists in your network, especially ones who don't usually watch YouTube!
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Backup Discord link - https://discord.gg/QWNPETtPcZ
Important Papers Playlist - https://youtube.com/playlist?list=PL6OLqxmk7RtyRkdJhXK8NWpT1krGNq1p4
----------------------------------------------------------------------------------------------------------------------------------
Links to articles discussed in this episode:
First paper – https://doi.org/10.1021/acs.joc.2c02000
Second paper – https://doi.org/10.1038/s41557-022-01027-7
Third paper – https://doi.org/10.1038/s41467-022-33827-3
Fourth paper – https://doi.org/10.1021/jacs.2c10010
Fifth paper – https://doi.org/10.1021/jacs.2c08244
B(4)−H Amination of o Carboranes - https://doi.org/10.1021/acs.orglett.2c02590
Aryl Azides to Aminopyridines - https://doi.org/10.1021/jacs.2c08464
Azetidine-Based Energetics - https://doi.org/10.1021/jacs.2c08191
Arylation of Iodocarboranes - https://doi.org/10.1021/acs.orglett.2c02648
Esters from Aryl Bromides - https://doi.org/10.1021/acs.orglett.2c03034
Photochemical Hydrosilylation of Alkenes - https://doi.org/10.1021/acs.joc.2c01885
Synthesis of Gedunin - https://doi.org/10.1021/jacs.2c09048
Pyrimidines and Quinazolines from Pyrazoles/Indazoles - https://doi.org/10.1021/jacs.2c09616
Vinyl Sulfides from Sulfoniums - https://doi.org/10.1021/acs.orglett.2c03095
Masked Aldehyde Radical Conjugate Addition - https://doi.org/10.1021/acscatal.2c03229
Enantioselective Dearomative Cyclization - https://doi.org/10.1002/anie.202207518
Ortho C-H Hydroxylation - https://doi.org/10.1021/jacs.2c08332
Boronic Ester [2+2] Cycloadditions and Total Syntheses - https://doi.org/10.1021/jacs.2c08777
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https://rumblevideoarchive.wordpress.com/
15
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Which Chemical is the Most Risky?
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Which chemicals carry the greatest risks? In this episode I discuss some compounds with the highest possible NFPA ratings, and we determine which ones are the most risky!
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
Speaking of risky, I have to say that molotay is remarkable.
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References:
Graduated Cylinder History Video - https://youtu.be/5TTu5Fx9T78
Hamilton Morris Podcast Episode - https://www.patreon.com/posts/73789212
Methylhydrazine Mycotoxin Video - https://www.youtube.com/watch?v=pkHTzVRVOp0
nBuLi Titration - https://doi.org/10.1016/S0022-328X(97)00143-5
Ether Peroxide Video - https://www.youtube.com/watch?v=D8tktdPSIso
NileRed Magnesium Silicide - https://www.youtube.com/watch?v=KXCBnznxxIk
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Molecules for this tierlist - tert-Butyl hydroperoxide, cyanogen, propargyl bromide, arsine, monomethylhydrazine, diazomethane, nickel tetracarbonyl, hydrogen cyanide, tert-butyllithium, acetaldehyde, trimethylaluminum, acrylonitrile, stibine, triethylaluminum, buli, butadiene, germane, ethylene oxide, TFE, trichlorosilane, pentaborane(9), diethyl ether hydroperoxide, dichlorosilane, vinyl chloride, diborane, picric acid, diethylaluminum chloride, silane
Tierlist Playlist - https://www.youtube.com/playlist?list=PL6OLqxmk7Rtx7YVG6hOgVHAgisH-y8yIW
https://rumblevideoarchive.wordpress.com/
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Which Nerve Agent is the Most Evil?
Like and subscribe. This is an archive channel, i'm not the owner of the content, check the link in the end. Nerve agents are completely terrifying - in this episode I discuss the different classes of nerve agents, and we determine which ones are the most EVIL.
Exposure to nerve agents is usually treated with atropine and pralidoxime chloride (2-PAM chloride).
Nerve agents inhibit acetylcholinesterase, which is an enzyme that catalyzes the breakdown of acetylcholine. Some nerve agents covalently bind to the enzyme, and can damage the active site of the enzyme, so the acetylcholine builds up, the signal keeps sending, and the motor neurons keep firing. The G series and V series of nerve agents were mass produced, weaponized agents, while the EA series, A series, and others are not known to be mass produced or weaponized.
Support the Channel on Patreon - https://www.patreon.com/thatchemist
Join the Community Discord! - https://discord.gg/thatchemist
Second Discord link if the first one is borked - https://discord.gg/QWNPETtPcZ
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References:
(Graphic) Rabbits exposed to nerve agents - https://www.youtube.com/watch?v=1J9rUdJ9HLM
Scary book - Jared Ledgard, A Laboratory History of Chemical Warfare Agents - (the link to this book was deactivated; perhaps the uploader had violated the hosting site's TOS - its ISBN-13 number is‎ 978-0615136455)
Methyl cyclosarin treatment patent - https://patents.google.com/patent/US10124043
Earliest Methyl cyclosarin reference - https://sci-hub.se/10.1007/BF00354767
Previous Tierlist - https://www.youtube.com/watch?v=xgjJBJdPCKw
Hydrolysis of VX/EA-2192 - https://doi.org/10.1289/ehp.99107933
VR 'first Novichok' - https://cen.acs.org/articles/96/i12/Nerve-agent-attack-on-spy-used-Novichok-poison.html
SL-599 (SB-8) paper - https://pubs.acs.org/doi/10.1021/ja01846a078
Perfect 10 patent - https://patents.google.com/patent/US4686293
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Molecules for this tierlist - Tabun (GA), Sarin (GB), Chlorosarin, Thiosarin (GBS), Soman (GD), Cyclosarin (GF), Methyl cyclosarin (EA-1356), VX, EA-2192, Russian VX (VR), Chinese VX, V-sub x, A-230, A-234, A-242, C01-A039, C01-A042, Neostigmine, TMTFA, TL-599 (SB-8), T-1123, T-1152, 4-692-530-01, 4-686-293-01 (Agent 1-10), 4-686-293-02 (Agent 1-8)
Tierlist Playlist - https://www.youtube.com/playlist?list=PL6OLqxmk7Rtx7YVG6hOgVHAgisH-y8yIW
https://rumblevideoarchive.wordpress.com/
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