Radical Photochemical Deoxygenation

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Important Papers covers various chemical reactions, mechanisms, and research papers in the field of organic chemistry, providing examples and explanations for each research paper.

In this video, I discuss five important papers in organic synthesis that were published around April 2023.

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References:
First Paper (Diethanolamine Boronates) - https://pubs.acs.org/doi/10.1021/acs.oprd.2c00342
Second Paper (Sulfones via Sulfonyl Fluorides) - https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.3c00447
Third Paper (Deoxygenation of Alcohols) - https://doi.org/10.1002/anie.202300178
Fourth Paper (Room Temp Ar-Br Amination) - https://doi.org/10.1021/jacs.3c00500
Fifth Paper (Desymmetrization of Boronates) - https://doi.org/10.1021/jacs.3c01571
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Honorable mentions:
Total Synthesis of (+)-Pedrolide - https://doi.org/10.1021/jacs.3c02113
Molybdenum(VI) Amide Activation - https://doi.org/10.1021/acs.joc.3c00218
Diastereoselective Synthesis of Cyclopropanes - https://doi.org/10.1002/ange.202303032
Tris(bicyclo[1.1.1]pentyl)phosphine - https://doi.org/10.1021/jacs.3c00885
Total Synthesis of Strempeliopidine - https://doi.org/10.1021/jacs.2c13146
Sulfonylation of Aryl Bromides - https://doi.org/10.1002/anie.202217623
Grayanane Diterpenoids - https://doi.org/10.1021/jacs.3c00753
Mechanochemical Birch - https://doi.org/10.1002/anie.202217723
Compact Rotaxane Superbases - https://doi.org/10.1021/jacs.3c01202
Dearomatization of arenes with tetrazinediones - https://doi.org/10.1021/jacs.3c02556
Enantioselective Divergent Syntheses of Cephalotaxus Alkaloids - https://doi.org/10.1021/jacs.3c01572
One-Bond-Nucleophilicity and -Electrophilicity Parameters: An Efficient Ordering System for 1,3-Dipolar Cycloadditions - https://pubs.acs.org/doi/full/10.1021/jacs.2c13872 – Mayr paper
Mayr’s N-parameter Database - https://www.cup.lmu.de/oc/mayr/reaktionsdatenbank2/
Waveform-controlled Electrosynthesis - https://doi.org/10.1126/science.adf4762
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