1967 Spider-Man in STING of the Scorpion

Spider-Man TV Series 1967–1970 TV-Y7 Original cartoon series based on the web-slinging Marvel comic book character, Peter Parker, who, after being bit by a radioactive spider, assumes extraordinary powers.
Creators: Stan Lee, Steve Ditko
Stars: Paul Soles, Peg Dixon, Paul Kligman
S01.E20 Sting of the Scorpion Episode aired Jan 20, 1968 TV-Y7
Carl Banas and Paul Kligman in Spider-Man (1967)
Your Friendly Neighborhood Spider-Man endures the Sting of the Scorpion
Writers: Phil Babet, Al Bertino, Lin Carter
Stars: Bernard Cowan, Paul Kligman, Paul Soles