1967 The Amazing Spider-Man vs The Power of Doctor Octopus

1967 Spider-Man Cartoon. Original cartoon series based on the web-slinging Marvel comic book character, Peter Parker, who, after being bit by a radioactive spider, assumes extraordinary powers.
Creators: Stan Lee, Steve Ditko
Stars: Paul Soles, Peg Dixon, Paul Kligman
S1.E1 The Power of Dr. Octopus Episode aired Sep 9, 1967
Vernon Chapman and Paul Soles in Spider-Man (1967)
Out in the countryside, Peter escapes an accident with the help of his Spider-Man disguise, but discovers a cave, with Dr.Octopus in charge of some power machines due to rule the World. Doc Ock captures Spidey, then Miss Brant who happened to be in the area.
Directors: Clyde Geronimi, Sid Marcus, Grant Simmons
Writers: Phil Babet, Al Bertino, Lin Carter
Stars: Bernard Cowan, Paul Kligman, Paul Soles