1992 Batman The Animated Series Fox Kids S01E03 Heart of Ice

Batman: The Animated Series TV Series 1992–1995
Billionaire Bruce Wayne secretly operates as Batman, a vigilante who battles a rouges' gallery of criminals and supervillains in Gotham City with the aid of various sidekicks and allies.
Creators Bill Finger, Bob Kane, Eric Radomski
Stars Kevin Conroy, Loren Lester, Efrem Zimbalist Jr.
S1.E3 Heart of Ice Episode aired Sep 7, 1992
Batman: The Animated Series (1992)
Brilliant cryogenics expert Dr. Victor Fries is transformed into Mr. Freeze, a vengeful creature who can only survive in subzero temperatures.
Director: Bruce Timm
Writers: Paul Dini, Bob Kane, Bill Finger
Stars: Kevin Conroy, Efrem Zimbalist Jr., Michael Ansara